Dusty wrote:
Quote:
but the next best thing is to use one of those "converter" type chemicals which bumps any rust present up to its highest (and most stable) oxidation state.
These actually work quite well on surfaces that have a good layer of firm (but not too thick) rust
Agreed
Dusty wrote:
They dont work so well on largely unrusted metel since they need the presence of rust for the reaction to take place.
I think the phosphoric acid based ones will - it just takes longer. Rust (the common brown rust at any rate) is Iron (III) oxide and the black stuff that you get after the acid is FePO4 - ferric phosphate. I think you can still get that on clean metal, it just needs more time and more acid to get there without the metal having first got to its (III) oxidation state.
Dusty wrote:
The problem with electrolysis is that it leaves the surface more or less rust free but highly reactive so a very thin oxide layer forms almost instantainiously on removal from the tank and washing.
What I am looking for is a primer that can chemically neutralise this sort of very thin layer and proivde an undercoat at the same time. I am sure such things were available in the past but no longer seem to be.
Another trick I have used on "Clean" surfaces was dipping in "Fernox DS9" (wwhich was a phosphoric acid bases central heating cleaner) this worked well and was sufficiently inexpensive that one could make up large tanks for dipping stuff in. It could also be used for removing heavier encrustations of rust but you had to be carefull about how you used it since it was quite aggressive)
Unfortunatly DS9 is no longer available (No doubt due to some sort of greenwash ecobabble!

) and although phosphoric acid is available "mail order" it seems jolly expensive compared to what I remember and I dont seem to be able to find out what concentration to use.
Ho Humm.
Is galvanising not an option? I live in the back end of nowhere and even here, there's a bloke who will call in, collect pretty much any part, big or small, and bring it back to me in a couple of weeks. I've had trailer chassis and garden gates galvanised before now by him - he just drives round collecting stuff until he's got a big enough load to make it worth taking to the galvanisers. OK, if you're getting a small part done, you have to wait a good while, but it's by far the best rust-prevention technique I've used. All paints get chipped, abraded and broken down by ultraviolet sooner or later. I know galvanising doesn't last forever, but it's usually good (depending on application) for many years and not as expensive as you'd think. Last time, I think it was something like a £1 per kilo - plus a surcharge for small components.